In the January/February issue of the magazine American Scientist, Chemistry Nobel Laureate Roald Hoffmann took exception to scientists applying the concept of aromaticity beyond organic molecules to ...
Aromaticity is one of chemistry’s oldest concepts to describe the behavior of molecules. Chemists created it 150 years ago to help visualize and explain the bonding, structure, and reactivity of ...
In 1862, a chemist nodded off in front of a fire and began to dream. August Kekulé had been pondering the most pressing question in his field at the time: what was the chemical structure of a curious ...
Aromaticity, a concept usually used to explain the striking stability and unusual reactivity of certain carbon-based molecules, could inspire the design of new catalysts with novel uses, KAUST ...
The term aromaticity is a basic, long-standing concept in chemistry that is well established for ring-shaped carbon compounds. Aromatic rings consisting solely of metal atoms were, however, heretofore ...
The concept of aromaticity underpins much of modern organic chemistry, describing the unusual stability and reactivity of cyclic molecules whose π-electrons are delocalised over a planar framework.
Scientists have achieved the first real-time visualization of how 'excited-state aromaticity' emerges within just hundreds of femtoseconds and then triggers a molecule to change from bent to planar ...
‘Controversial’, ‘ suspicious ’, ‘questionable’ and even ‘ an exercise in chemical futility ’ – these are only some of the ways scientists have described the concept of aromaticity. And that’s in ...
The term aromaticity was initially introduced to describe the properties of molecules with special aromatic odor, such as benzene, and now is considered as one of the most important concepts in ...
Anti-aromatic compounds, as well as small cyclic alkynes or carbynes, are particularly challenging synthetic goals. The combination of their destabilizing features hinders attempts to prepare ...